Synthesis of N-phytochlorin-substituted (60)fulleropyrrolidines

被引：17

作者：

Efimov, A

Tkatchenko, NV

Vainiotalo, P

Lemmetyinen, H

机构：

[1] Tampere Univ Technol, Inst Mat Chem, FIN-33101 Tampere, Finland

[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2001年 / 5卷 / 12期

基金：

芬兰科学院;

关键词：

pheophorbide; phytochlorin; fullerene; photoinduced electron transfer; donor-acceptor dyad;

D O I：

10.1002/jpp.550

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of new phytochlorin-fullerene dyads was prepared. Synthetic pathway includes attachment of glycine to aldehyde-containing phytochlorins via reductive amination, where 3- and 7-carbonyl-substituted pheophorbides exhibit surprisingly different reactivity. The appropriate conditions of reactions (e.g. solvents and reducing agents) were determined in each case. Copyright (C) 2001 John Wiley Sons, Ltd.

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收藏

页码：835 / 838

页数：4

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