Structural measurements of hydrogen-bonded complexes of perylene with water and methanol

被引:10
作者
Andrews, PM
Pryor, BA
Palmer, PM
Topp, MR
机构
[1] Department of Chemistry, University of Pennsylvania, Philadelphia
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0009-2614(96)01409-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rotational coherence experiments have been carried out for 1:1 van der Waals complexes of perylene with water and methanol. The observed inertial properties are consistent with structures corresponding to potential-energy minima calculated via MM2 techniques. The results show that both types of complex involve hydrogen-bonding to pi-electrons on the perimeter of the aromatic molecule.
引用
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页码:224 / 230
页数:7
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