Underfill of flip chip on organic substrate: viscosity, surface tension, and contact angle

In flip-chip packaging, an underfill is dispensed on one or two adjacent sides of the die. The underfill is driven by a capillary flow to fill the gap between the die and substrate. The application of an underfill reduces the stress to solder bumps and enhances the reliability of the solder joints. Underfill materials consist of epoxy or cyanate ester resins, catalyst, crosslinker, wetting agent, pigment, and fillers. Underfill materials are highly filled with the filler loading ranging from 40% to 70%. In terms of underfill material processing, fast flow and curing are desired for high throughput. The viscosity, surface tension, and contact angle are key material properties affecting the gap filling process. In order to achieve fast filling, it is required that an underfill material has low viscosity and low contact angle at dispensing temperatures. Due to curing of an underfill material at dispensing temperature, the viscosity increases with time, which complicates the underfill flow process. The rheological behavior of several underfill materials was experimentally studied. All the underfill materials showed strong temperature dependence in viscosity before the curing. The time dependent viscosity and curing of underfill materials were examined by a dynamic time sweep test. The effects of viscosity and curing behavior of underfill materials on underfill material processing were investigated. The material with a longer gel time had more stable viscosity at room temperature, and therefore longer pot life. Experimental methods were developed to measure the surface tension and the contact angle of underfills at temperatures over 100 degreesC. Results showed that the contact angle for underfill on a substrate was time dependent. The interaction between underfill and substrate affects not only gap filling, but also Meting. The effect of surface energies of flip-chip substrates on wetting angles was also studied. Experiment results showed that for the same underfill, the higher the surface energy of substrate, the better the filleting. (C) 2002 Elsevier Science Ltd. All rights reserved.