Solid-phase extraction of phenol and chlorophenols in water with a chemically modified polymer-supported tetrakis(p-carboxyphenyl) porphyrin (H2TCPP)

被引：16

作者：

Kim, DG

Jung, MW

Paeng, IR

Rhee, JS

Paeng, KJ ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Wonju 220710, South Korea

[2] Seoul Womens Univ, Dept Chem, Seoul 139774, South Korea

[3] KIST, Water Environm Res Ctr, Seoul 136791, South Korea

来源：

MICROCHEMICAL JOURNAL | 1999年 / 63卷 / 01期

关键词：

chemically modified sorbent; solid-phase extraction; phenol; chlorophenols; tetrakis(p-carboxyphenyl)porphyrin; XAD-2; XAD-4;

D O I：

10.1006/mchj.1999.1775

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A chemically modified sorbent was evaluated as a preconcentration substrate in solid-phase extraction of phenol and chlorophenols. Tetrakis(p-carboxyphenyl) porphyrin (H2TCPP) was chemically bonded to porous polymeric XAD resins by ketone linkage. Breakthrough volumes, recovery values, and detection Limits were determined. The synthesized sorbent showed higher recoveries in tap water than commercially available sorbents such as XAD-2 and XAD-4. (C) 1999 Academic Press.

引用

收藏

页码：134 / 139

页数：6

相关论文

共 17 条

[1] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].

ADLER, AD ;

LONGO, FR ;

FINARELLI, JD ;

GOLDMACH.J ;

ASSOUR, J ;

KORSAKOF.L .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) :476-+

[2] A REVIEW OF SOLID-PHASE EXTRACTION - BASIC PRINCIPLES AND NEW DEVELOPMENTS [J].

BERRUETA, LA ;

GALLO, B ;

VICENTE, F .

CHROMATOGRAPHIA, 1995, 40 (7-8) :474-483

[3] DETERMINATION OF CHLOROANILINE TRACES IN ENVIRONMENTAL WATERS BY SELECTIVE EXTRACTION WITH 2 TRAPS IN TANDEM AND LIQUID-CHROMATOGRAPHY [J].

DICORCIA, A ;

SAMPERI, R .

ANALYTICAL CHEMISTRY, 1990, 62 (14) :1490-1494

[4]

DICORCIA A, 1994, J AOAC INT, V77, P446

[5] USE OF PYROCARBON SORBENTS FOR TRACE ENRICHMENT OF POLAR COMPOUNDS FROM AQUEOUS SAMPLES WITH ONLINE HPLC ANALYSIS [J].

GOLKIEWICZ, W ;

WERKHOVENGOEWIE, CE ;

BRINKMAN, UAT ;

FREI, RW ;

COLIN, H ;

GUIOCHON, G .

JOURNAL OF CHROMATOGRAPHIC SCIENCE, 1983, 21 (01) :27-33

[6] Mixed mode SPE of pollutants in water on mechanically blended silica-based bonded phases .1. Influence of the preparation method [J].

Hajouj, Z ;

Thomas, J ;

Siouffi, AM .

JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES, 1996, 19 (12) :1937-1945

[7]

HENNION MC, 1994, ENVIRON SCI TECHNOL, V28, pA576, DOI 10.1021/es00062a717

[8] SHAPE-SELECTIVE SEPARATION OF POLYCYCLIC AROMATIC-HYDROCARBONS BY REVERSED-PHASE LIQUID-CHROMATOGRAPHY ON TETRAPHENYLPORPHYRIN-BASED STATIONARY PHASES [J].

KIBBEY, CE ;

MEYERHOFF, ME .

JOURNAL OF CHROMATOGRAPHY, 1993, 641 (01) :49-55

[9] Solid-phase extraction of phenols and pesticides in water with a modified polymeric resin [J].

Masque, N ;

Galia, M ;

Marce, RM ;

Borrull, F .

ANALYST, 1997, 122 (05) :425-428

[10]

MONTGOMERY JM, 1985, WATER TREATMENT PRIN, P385