Fabrication of all solid-state lithium-ion batteries with three-dimensionally ordered composite electrode consisting of Li0.35La0.55TiO3 and LiMn2O4

被引：70

作者：

Hara, Masanori ^{[1
]}

Nakano, Hiroyuki ^{[1
,2
]}

Dokko, Kaoru ^{[3
]}

Okuda, Sayaka ^{[1
]}

Kaeriyama, Atsushi ^{[1
]}

Kanamura, Kiyoshi ^{[1
,2
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Appl Chem, Tokyo 1920397, Japan

[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan

[3] Yokohama Natl Univ, Dept Chem & Biotechnol, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan

来源：

JOURNAL OF POWER SOURCES | 2009年 / 189卷 / 01期

关键词：

3-Dimensionally ordered macroporous; Li0.35La0.55TiO3; LiMn2O4; All solid state; Solid electrolyte; MICROPHASE SEPARATION STRUCTURE; POLYMER ELECTROLYTE; TITANIUM PHOSPHATE; CONDUCTIVITY; INTERFACE;

D O I：

10.1016/j.jpowsour.2008.12.048

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A composite electrode between three-dimensionally ordered macroporous (3DOM) Li0.35La0.55TiO3 (LLT) and LiMn2O4 was fabricated by colloidal crystal templating method and sol-gel process. A close-packed PS beads with the opal structure was prepared by filtration of a suspension containing PS beads. Li-La-Ti-O sol was injected by Vacuum impregnation process into the voids between PS beads, and then was heated to form 3DOM-LLT. Three-dimensionally ordered composite material consisting of LiMn2O4 and LLT was prepared by sol-gel process. The prepared composite was characterized with SEM and XRD. All solid-state Li-ion battery was fabricated with the LLT-LiMn2O4 composite electrode as a cathode, dry polymer electrolyte and Li metal anode. The prepared all solid-state cathode exhibited a volumetric discharge capacity of 220 mAh cm(-3). (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：485 / 489

页数：5

共 21 条

[1] Lithium ion transfer at the interface between lithium-ion-conductive solid crystalline electrolyte and polymer electrolyte [J].

Abe, T ;

Ohtsuka, M ;

Sagane, F ;

Iriyama, Y ;

Ogumi, Z .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (11) :A1950-A1953

[2] IONIC-CONDUCTIVITY OF THE LITHIUM TITANIUM PHOSPHATE (LI1+XALXTI2-X(PO4)3), (LI1+XSCXTI2-X(PO4)3), (LI1+XYXTI2-X(PO4)3), (LI1+XLAXTI2-X(PO4)3 SYSTEMS [J].

AONO, H ;

SUGIMOTO, E ;

SADAOKA, Y ;

IMANAKA, N ;

ADACHI, GY .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (02) :590-591

[3] IONIC-CONDUCTIVITY OF SOLID ELECTROLYTES BASED ON LITHIUM TITANIUM PHOSPHATE [J].

AONO, H ;

SUGIMOTO, E ;

SADAOKA, Y ;

IMANAKA, N ;

ADACHI, G .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (04) :1023-1027

[4] Comparative study of lithium ion conductors in the system Li1-xAlxA2-xIV (PO4)3 with AIV = Ti or Ge and 0≤x≤0.7 for use as Li+ sensitive membranes [J].

Cretin, M ;

Fabry, P .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (16) :2931-2940

[5] A high-rate, long-life, lithium nanocomposite polymer electrolyte battery [J].

Croce, F ;

Fiory, FS ;

Persi, L ;

Scrosati, B .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (08) :A121-A123

[6] Preparation of three dimensionally ordered macroporous Li0.35La0.55TiO3 by colloidal crystal templating process [J].

Dokko, K ;

Akutagawa, N ;

Isshiki, Y ;

Hoshina, K ;

Kanamura, K .

SOLID STATE IONICS, 2005, 176 (31-34) :2345-2348

[7] Preparation of LiMn2O4 thin-film electrode on Li1+xAlxTi2-x(PO4)3 NASICON-type solid electrolyte [J].

Dokko, Kaoru ;

Hoshina, Keigo ;

Nakano, Hiroyuki ;

Kanamura, Kiyoshi .

JOURNAL OF POWER SOURCES, 2007, 174 (02) :1100-1103

[8] Superionic conductivity of glass-ceramics in the system Li2O-Al2O3-TiO2-P2O5 [J].

Fu, J .

SOLID STATE IONICS, 1997, 96 (3-4) :195-200

[9] Formation of electrode-electrolyte interface by lithium insertion to SnS-P2S5 negative electrode materials in all-solid-state cells [J].

Hayashi, Akitoshi ;

Konishi, Takanori ;

Tadanaga, Kiyoharu ;

Tatsumisago, Masahiro .

SOLID STATE IONICS, 2006, 177 (26-32) :2737-2740

[10] Investigation on electrochemical interface between Li4Ti5O12 and Li1+xAlxTi2-x(PO4)3 NASICON-type solid electrolyte [J].

Hoshina, K ;

Dokko, K ;

Kanamura, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) :A2138-A2142

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