Core-shell structured sulfur-polypyrrole composite cathodes for lithium-sulfur batteries

被引:211
作者
Fu, Yongzhu [1 ]
Manthiram, Arumugam
机构
[1] Univ Texas Austin, Electrochem Energy Lab, Austin, TX 78712 USA
来源
RSC ADVANCES | 2012年 / 2卷 / 14期
关键词
POSITIVE ELECTRODE MATERIALS; CONDUCTING POLYMER; PERFORMANCE;
D O I
10.1039/c2ra20393f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A sulfur-polypyrrole composite cathode with a core-shell structure consisting of spherical sulfur particles coated with polypyrrole has been developed. The conductive polypyrrole coating on the sulfur facilitates fast electron transport enabling the material with superior electrochemical stability, rate capability, and cyclability in lithium-sulfur batteries.
引用
收藏
页码:5927 / 5929
页数:3
相关论文
共 29 条
[1]   Li/S fundamental chemistry and application to high-performance rechargeable batteries [J].
Akridge, JR ;
Mikhaylik, YV ;
White, N .
SOLID STATE IONICS, 2004, 175 (1-4) :243-245
[2]  
Bubnova O, 2011, NAT MATER, V10, P429, DOI [10.1038/NMAT3012, 10.1038/nmat3012]
[3]   Sandwich-type functionalized graphene sheet-sulfur nanocomposite for rechargeable lithium batteries [J].
Cao, Yuliang ;
Li, Xiaolin ;
Aksay, Ilhan A. ;
Lemmon, John ;
Nie, Zimin ;
Yang, Zhenguo ;
Liu, Jun .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (17) :7660-7665
[4]   Positive Electrode Materials for Li-Ion and Li-Batteries [J].
Ellis, Brian L. ;
Lee, Kyu Tae ;
Nazar, Linda F. .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :691-714
[5]   Synthesis and characterization of polypyrrole nanofibers with different dopants [J].
Goel, Shubhra ;
Mazumdar, Nasreen A. ;
Gupta, Alka .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2010, 21 (03) :205-210
[6]   Electrochemically Fabricated Polypyrrole-Cobalt-Oxygen Coordination Complex as High-Performance Lithium-Storage Materials [J].
Guo, Bingkun ;
Kong, Qingyu ;
Zhu, Ying ;
Mao, Ya ;
Wang, Zhaoxiang ;
Wan, Meixiang ;
Chen, Liquan .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (52) :14878-14884
[7]   Sulfur-Impregnated Disordered Carbon Nanotubes Cathode for Lithium-Sulfur Batteries [J].
Guo, Juchen ;
Xu, Yunhua ;
Wang, Chunsheng .
NANO LETTERS, 2011, 11 (10) :4288-4294
[8]   High "C" rate Li-S cathodes: sulfur imbibed bimodal porous carbons [J].
He, Guang ;
Ji, Xiulei ;
Nazar, Linda .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (08) :2878-2883
[9]  
Jang J, 2002, ANGEW CHEM INT EDIT, V41, P4016, DOI 10.1002/1521-3773(20021104)41:21<4016::AID-ANIE4016>3.0.CO
[10]  
2-G