The structure of colloid-polymer mixtures

被引:37
作者
Louis, AA [1 ]
Finken, R [1 ]
Hansen, JP [1 ]
机构
[1] Univ Cambridge, Chem Labs, Cambridge CB2 1EW, England
来源
EUROPHYSICS LETTERS | 1999年 / 46卷 / 06期
关键词
D O I
10.1209/epl/i1999-00327-4
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We investigate the structure of colloid-polymer mixtures by calculating the structure factors for the Asakura-Oosawa model in the PY approximation. We discuss the role of potential range, polymer concentration and polymer-polymer interactions on the colloid-colloid structure. Our results compare reasonably well with the recent experiments of Moussaid et al. (MOUSSAID A., POON W. C. K., PUSEY P. N. and SOLIVA M. F., Phys. Rev. Lett., 82 (1999) 225) for small wave number k, but we find that the Hansen-Verlet freezing criterion is violated when the liquid phase becomes marginal.
引用
收藏
页码:741 / 747
页数:7
相关论文
共 17 条
[1]   ON INTERACTION BETWEEN 2 BODIES IMMERSED IN A SOLUTION OF MACROMOLECULES [J].
ASAKURA, S ;
OOSAWA, F .
JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (07) :1255-1256
[2]   Integral equation theory description of phase equilibria in classical fluids [J].
Caccamo, C .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1996, 274 (1-2) :1-105
[3]   Microscopic theory of polymer-mediated interactions between spherical particles [J].
Chatterjee, AP ;
Schweizer, KS .
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (23) :10464-10476
[4]  
DAUTENHAHN J, 1994, MACROMOLECULES, V27, P5299
[5]  
DIJKSTRA M, 1999, IN PRESS PHYS REV E, V59
[6]   Universal density-force relations for polymers near a repulsive wall [J].
Eisenriegler, E .
PHYSICAL REVIEW E, 1997, 55 (03) :3116-3123
[7]  
GAST AP, 1983, J COLLOID INTERF SCI, V96, P1437
[8]  
Hansen J P., 2013, Theory of Simple Liquids: With Applications to Soft Matter
[9]   PHASE-BEHAVIOR OF A MODEL COLLOID-POLYMER MIXTURE [J].
ILETT, SM ;
ORROCK, A ;
POON, WCK ;
PUSEY, PN .
PHYSICAL REVIEW E, 1995, 51 (02) :1344-1352
[10]   THERMODYNAMIC PROPERTIES OF MIXTURES OF HARD SPHERES [J].
LEBOWITZ, JL ;
ROWLINSON, JS .
JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (01) :133-&