Nanocomposite multilayer film of a ruthenium metallodendrimer and a Dawson-type polyoxometalate as a bifunctional electrocatalyst

被引：119

作者：

Cheng, L ^{[1
]}

Cox, JA ^{[1
]}

机构：

[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

来源：

CHEMISTRY OF MATERIALS | 2002年 / 14卷 / 01期

关键词：

D O I：

10.1021/cm010854y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A pentaerythiritol-based metallodendrimer with four ruthenium(II) terpyridine units (RuDen) and a Dawson-type phosphotungstate, P(2)W(18)O(62)(6-) (P(2)W(18)) are immobilized on a glassy carbon electrode to form multilayered self-assemblies by layer-by-layer deposition based on electrostatic interaction. The (P(2)W(18)\RuDen) multi-layer films have been investigated with UV-visible spectrometry, cyclic voltammetry, and TappingMode atomic force microscopy. They showed a bifunctional electrocatalytic capability, namely, iodate reduction and arsenite oxidation.

引用

页码：6 / +

页数：4

共 29 条

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