Photochemical Processes Revealed by X-ray Transient Absorption Spectroscopy

被引：69

作者：

Chen, Lin X. ^{[1
,3
]}

Zhang, Xiaoyi ^{[2
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Xray Sci Div, Adv Photon Source, Argonne, IL 60439 USA

[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2013年 / 4卷 / 22期

关键词：

MULTIPLE-SCATTERING CALCULATIONS; TRANSITION-METAL-COMPLEXES; FINE-STRUCTURE TECHNIQUE; TRIPLET EXCITED-STATE; TIME-RESOLVED EXAFS; FREE-ELECTRON LASER; STRUCTURAL DYNAMICS; MOLECULAR-DYNAMICS; CHARGE-TRANSFER; DIIMINE-COMPLEXES;

D O I：

10.1021/jz401750g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

After over a decade of development, X-ray transient absorption (XTA) spectroscopy has become an increasingly important and common tool in following molecular structures in chemical reactions and to map out structural factors that could influence reaction pathways. The Perspective reviews current achievements and capabilities in chemical dynamics from XTA spectroscopy based mainly on studies by the authors, collaborators, and cousers of the same facility and then outlines some future challenges and impacts in chemical sciences using pulsed X-rays from the third-generation synchrotron and the fourth-generation X-ray free-electron light sources.

引用

页码：4000 / 4013

页数：14

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