Deprotonation of low-spin mononuclear iron(III)-hydroperoxide complexes give transient blue species assigned to high-spin iron(III)-peroxide complexes

被引：81

作者：

Jensen, KB ^{[1
]}

McKenzie, CJ ^{[1
]}

Nielsen, LP ^{[1
]}

Pedersen, JZ ^{[1
]}

Svendsen, HM ^{[1
]}

机构：

[1] Univ So Denmark, Dept Chem, DK-5230 Odense M, Denmark

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 14期

关键词：

D O I：

10.1039/a902985k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Purple iron(III)-hydroperoxide complex ions [Fe(Rtpen)(eta(1)-OOH)](2+) can be reversibly deprotonated to give transient blue species showing spectroscopic properties consistent with iron(III)-peroxide complexes; a novel ferryl species is produced in MS/MS experiments with the iron(III) hydroperoxide ion.

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页码：1313 / 1314

页数：2

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