BING-1:: a tin-oxalate-sodium-fluoride framework, Na4Sn4(C2O4)3F6

被引：19

作者：

Salami, TO

Zavalij, PY

Oliver, SRJ ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

[2] SUNY Binghamton, Mat Res Ctr, Binghamton, NY 13902 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801002409

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

BING-1 [tetrasodium tetratin tris(oxalate) hexafluoride] was synthesized solvothermally at 423 K and crystallized in the triclinic system, with the P (1) over bar space group. The asymmetric unit consists of two types of tin(II) centres, connected by oxalate groups. The Sn atoms are also bonded to fluoride ions, which bond the tin oxalate layers together via interlayer Na atoms, to define a three-dimensional framework.

引用

页码：m111 / m113

页数：3

共 9 条

[1] Tin(II) oxalates synthesized in the presence of structure-directing organic amines: Members of a potentially vast class of new open-framework and related materials [J].