Solvent reorganization energies and local densities of Coumarin 153 (C153) in supercritical C2H6, CO2, and CHF3 (T-c = 5 K) are measured using fluorescence spectroscopy. Reorganization energies are 320 +/- 70 and 770 +/- 70 cm(-1) in CO2 and CHF3, respectively - nearly independent of density (0.3 less than or equal to rho/rho(c) less than or equal to 2.1). The spectral shifts imply similar effective local densities in all three solvents. These effective densities can exceed 3-5 times the bulk density. In CO, and CHF,, the maximum density augmentation calculated from emission shifts is similar to 20% greater than that calculated from excitation shifts. No such difference is found in C2H6. (C) 1999 Elsevier Science B.V. All rights reserved.