Polymorphism and disorder in oligo- and polyanilines.

被引：8

作者：

Folch, S

Gruger, A

Régis, A

Baddour-Hadjean, R

Colomban, P

机构：

[1] CNRS, UPR 1580, LADIR, F-94320 Thiais, France

[2] Off Natl Etud & Rech Aerosp, DMSC, F-92322 Chatillon, France

来源：

SYNTHETIC METALS | 1999年 / 101卷 / 1-3期

关键词：

IR and Raman spectroscopies; neutron scattering; polyanilines;

D O I：

10.1016/S0379-6779(98)00797-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The short-range structure and disorder of polyanilines is discussed by considering backbone geometry, conformation and sp(2)/sp(3) hybridization of nitrogen atom. The comparison between polymer and oIigomer spectra shows that ring deformation modes are very sensitive to static/dynamic disorder. Low energy Raman and inelastic neutron allow to distinguish two class of emeraldine salts (ES I/ES-II) already distinguished from X-Ray Powder patterns.

引用

页码：795 / 796

页数：2

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