Plants in organic synthesis: an alternative to baker's yeast

被引：45

作者：

Bruni, R

Fantin, G

Medici, A

Pedrini, P

Sacchetti, G

机构：

[1] Univ Ferrara, Dipartimento Risorse Nat & Culturali, I-44100 Ferrara, Italy

[2] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(02)00514-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction of acetophenone 1 and the hydrolysis of 1-acetoxy-2-methylcyclohexene 3 with various commercially available plants to the corresponding S-carbinol 2 and S-ketone 4 are described. The further incubation of 2-methylcyclohexanone 4 with some plants affords the enantiomerically pure trans- and/or cis-alcohol 5 and 6, respectively. (C) 2002 Elseveir Science Ltd. All rights reserved.

引用

收藏

页码：3377 / 3379

页数：3

相关论文

共 16 条

[1] Preparative synthesis of chiral alcohols by enantioselective reduction with Daucus carota root as biocatalyst [J].

Baldassarre, F ;

Bertoni, G ;

Chiappe, C ;

Marioni, F .

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2000, 11 (01) :55-58

[2] ABILITY OF PLANT CALLUS-CULTURES TO SYNTHESIZE AND ACCUMULATE LOWER TERPENOIDS [J].

BANTHORPE, DV ;

BRANCH, SA ;

NJAR, VCO ;

OSBORNE, MG ;

WATSON, DG .

PHYTOCHEMISTRY, 1986, 25 (03) :629-636

[3] MONOTERPENE AND SESQUITERPENE BIOSYNTHESIS IN PLANT-CELLS IN CULTURE .2. THE CONTROL OF CALLUS FORMATION AND DIFFERENTIATION IN SCENTED PELARGONIUMS [J].

BROWN, JT ;

CHARLWOOD, BV .

JOURNAL OF PLANT PHYSIOLOGY, 1986, 123 (05) :409-417

[4] ASYMMETRIC HYDROLYZES OF 1,2-DIACETOXYCYCLOHEXANES BY THE CULTURED SUSPENSION CELLS OF MARCHANTIA-POLYMORPHA [J].

GOTOH, S ;

AOKI, M ;

IWAEDA, T ;

IZUMI, S ;

HIRATA, T .

CHEMISTRY LETTERS, 1994, (08) :1519-1520

[5] ENANTIOSELECTIVITY IN THE REDUCTION OF ALPHA-DICARVELONE BY CELL-SUSPENSION CULTURES OF NICOTIANA-TABACUM [J].

HAMADA, H ;

NAKAMURA, N ;

ITO, S ;

KAWABE, S ;

FUNAMOTO, T .

PHYTOCHEMISTRY, 1988, 27 (12) :3807-3808

[6] ENANTIOSELECTIVITY IN THE BIOTRANSFORMATION OF MONOCYCLIC AND BICYCLIC MONOTERPENOIDS WITH THE CULTURED-CELLS OF NICOTIANA-TABACUM [J].

HAMADA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (03) :869-878

[7] THE BIOTRANSFORMATION OF FOREIGN SUBSTRATES BY TISSUE-CULTURE .2. STEREOSELECTIVITY OF THE REDUCTION OF CARVONE AND DIHYDROCARVONE BY SUSPENSION CELLS OF NICOTIANA-TABACUM [J].

HIRATA, T ;

HAMADA, H ;

AOKI, T ;

SUGA, T .

PHYTOCHEMISTRY, 1982, 21 (09) :2209-2212

[8] REDUCTION OF ALPHA,BETA-UNSATURATED KETONES BY PLANT SUSPENSION-CULTURES [J].

KERGOMARD, A ;

RENARD, MF ;

VESCHAMBRE, H ;

COURTOIS, D ;

PETIARD, V .

PHYTOCHEMISTRY, 1988, 27 (02) :407-409

[9] BIOTRANSFORMATION OF MONOTERPENOIDS BY SUSPENSION-CULTURES OF LAVANDULA-ANGUSTIFOLIA [J].

LAPPIN, GJ ;

STRIDE, JD ;

TAMPION, J .

PHYTOCHEMISTRY, 1987, 26 (04) :995-997

[10]

MORRIS P, 1986, SECONDARY METABOLISM