Transmetallation reactions of planar chiral cyclopalladated ferrocenylimines with metallic mercury

被引：40

作者：

Cui, XL ^{[1
]}

Wu, YJ ^{[1
]}

Du, CX ^{[1
]}

Yang, L ^{[1
]}

Zhu, Y ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 07期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0957-4166(99)00122-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of optically active 2-chloromercurio-1-[1-(arylimino)ethyl] ferrocenes was synthesized by transmetallation of optically active cyclopalladated ferrocene derivatives with metallic mercury. The structure and absolute configuration of complexes Rp-4b were determined by X-ray diffraction, on the basis of which and the CD spectra the absolute configuration of other optically active compounds was ascertained. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1255 / 1262

页数：8

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