First enantioselective catalysis using a helical diphosphane

被引：200

作者：

Reetz, MT

Beuttenmuller, EW

Goddard, R

机构：

[1] Max-Planck-Inst. fur Kohlenforschung, D-45470 Mülheim/Ruhr

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(97)00562-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of 2,15-bis(diphenylphosphino)-hexahelicene (PHelix) in enantiomerically pure form and its use as a helical ligand for enantioselective rhodium-catalyzed hydrogenation are described. (C) 1997 Elsevier Science Ltd.

引用

页码：3211 / 3214

页数：4

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