High performance carbon nanotube-Si core-shell wires with a rationally structured core for lithium ion battery anodes

被引:66
作者
Fan, Yu [1 ]
Zhang, Qing [1 ]
Lu, Congxiang [1 ]
Xiao, Qizhen [1 ]
Wang, Xinghui [1 ]
Tay, Beng Kang [1 ]
机构
[1] Nanyang Technol Univ, Sch Elect & Elect Engn, Nanoelect Ctr Excellence, NOVITAS, Singapore 639798, Singapore
关键词
NEGATIVE ELECTRODES; SILICON; ARRAYS; CAPACITY;
D O I
10.1039/c3nr33683b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Core-shell Si nanowires are very promising anodematerials. Here, we synthesize vertically aligned carbon nanotubes (CNTs) with relatively large diameters and large inter-wire spacing as core wires and demonstrate a CNT-Si core-shell wire composite as a lithium ion battery (LIB) anode. Owing to the rationally engineered core structure, the composite shows good capacity retention and rate performance. The excellent performance is superior to most core-shell nanowires previously reported.
引用
收藏
页码:1503 / 1506
页数:4
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