Design and synthesis of metal-carboxylate frameworks with permanent microporosity

被引：78

作者：

Eddaoudi, M

Li, HL

Reineke, T

Fehr, M

Kelley, D

Groy, TL

Yaghi, OM

机构：

[1] Arizona State Univ, Dept Chem & Biochem, Supramol Design & Discovery Grp, Tempe, AZ 85287 USA

[2] Nalco Chem Co, Naperville, IL 60563 USA

来源：

TOPICS IN CATALYSIS | 1999年 / 9卷 / 1-2期

关键词：

metal-organic; microporous; frameworks; sorption; isotherm;

D O I：

10.1023/A:1019110622091

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Metal-carboxylate clusters are ideally suited as secondary building units (SBU) for the assembly of extended open frameworks. Examples extracted from the chemistry of the multidentate building block 1,4-benzenedicarboxylate (BDC) show that Zn(BDC) clusters lead to the formation of rigid, stable and truly microporous metal-carboxylate networks. Gas sorption isotherms measured for this class of materials show type (I) gas uptake that is analogous to those observed for zeolites and molecular sieves.

引用

页码：105 / 111

页数：7

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