Coordination-driven self-assembly of functionalized supramolecular metallacycles

被引：290

作者：

Northrop, Brian H. ^{[1
]}

Yang, Hai-Bo ^{[1
]}

Stang, Peter J. ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 45期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1039/b811712h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordination-driven self-assembly that combines rigid ditopic Pt(II) metal acceptors and bis-pyridyl organic donors provides a facile means of synthesizing well-defined metallacycles of predetermined size and geometry. Functionalization of the component acceptor or donor building blocks allows for the preparation of multifunctional supramolecular materials wherein the stoichiometry and position of individual functional moieties can be precisely controlled. The design, self-assembly, and applications of polyfunctional supramolecules incorporating functional moieties with host-guest, photonic, materials, and self-organizational properties is discussed.

引用

页码：5896 / 5908

页数：13

共 157 条

[1] Fiber-optic evanescent wave biosensor for the detection of oligonucleotides [J].

Abel, AP ;

Weller, MG ;

Duveneck, GL ;

Ehrat, M ;

Widmer, HM .

ANALYTICAL CHEMISTRY, 1996, 68 (17) :2905-2912

[2] Synthesis of a bis(pyridyl)-substituted perylene diimide ligand and incorporation into a supramolecular rhomboid and rectangle via coordination driven self-assembly [J].

Addicott, C ;

Oesterling, I ;

Yamamoto, T ;

Müllen, K ;

Stang, PJ .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (03) :797-801

[3]

[Anonymous], 1960, ENG SCI, DOI [DOI 10.1109/84.128057, 10.1109/84.128057]

[4] Assembly of dendrimers with redox-active [{CpFe(μ3-CO)}4] clusters at the periphery and their application to oxo-anion and adenosine-5′-triphosphate sensing [J].

Aranzaes, JR ;

Belin, C ;

Astruc, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) :132-136

[5] Toward photoswitchable dendritic hosts.: Interaction between azobenzene-functionalized dendrimers and eosin [J].

Archut, A ;

Azzellini, GC ;

Balzani, V ;

De Cola, L ;

Vögtle, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (47) :12187-12191

[6] Electron and proton reservoir complexes: Thermodynamic basis for C-H activation and applications in redox and dendrimer chemistry [J].

Astruc, D .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) :287-298

[7] Block copolymers - Designer soft materials [J].

Bates, FS ;

Fredrickson, GH .

PHYSICS TODAY, 1999, 52 (02) :32-38

[8] In touch with atoms [J].

Binnig, G ;

Rohrer, H .

REVIEWS OF MODERN PHYSICS, 1999, 71 (02) :S324-S330

[9] High-throughput synthesis of nanoscale materials:: Structural optimization of functionalized one-step star polymers [J].

Bosman, AW ;

Heumann, A ;

Klaerner, G ;

Benoit, D ;

Fréchet, JMJ ;

Hawker, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (26) :6461-6462

[10] Crown ethers: The search for selective ion ligating agents [J].

Bradshaw, JS ;

Izatt, RM .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (08) :338-345

← 1 2 3 4 5 6 7 8 9 10 →