Synthesis and structure of K2[HMo6(VI)V(V)O22(NH3CH2COO)3]•8H2O:: a new example of a polyoxomolybdovanadate coordinated by a glycinato ligand

被引：36

作者：

Cindric, M ^{[1
]}

Strukan, N ^{[1
]}

Devcic, M ^{[1
]}

Kamenar, B ^{[1
]}

机构：

[1] Univ Zagreb, Fac Sci, Lab Gen & Inorgan Chem, HR-10001 Zagreb, Croatia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 11期

关键词：

molybdovanadates; glycine; carboxylato ligand; crystal structures;

D O I：

10.1016/S1387-7003(99)00141-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new complex of formula K-2[(HMo6VO22)-V-VI-O-V(NH3CH2COO)(3)] . 8H(2)O has been prepared from molybdenum(VI)) oxide and vanadium(V) oxide in aqueous solution by adding glycine and potassium chloride, and its structure determined by X-ray structure analysis. The molybdovanadate anion is built up of six MoO6 edge-sharing octahedra connected into a ring centered by a VO4 tetrahedron. The MoO6 octahedra are in pairs linked by the bridging glycine-carboxylato ligands. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：558 / 560

页数：3

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