Improved electron injection in polymer light-emitting diodes using anionic conjugated polyelectrolyte

被引:24
作者
Jin, Youngeup [1 ]
Bazan, Guillermo C. [1 ]
Heeger, Alan J. [1 ]
Kim, Jin Young [2 ]
Lee, Kwanghee [2 ]
机构
[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
[2] GIST, Dept Mat Sci & Engn, Heeger Ctr Adv Mat, Kwangju 500712, South Korea
关键词
D O I
10.1063/1.2989133
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report improved performance in polymer light-emitting diodes incorporating conjugated polyelectrolytes as an electron injection layer (EIL). When we introduce water soluble conjugated polymers, poly[9,9'-bis(4-sulfonatobutyl)fluorene-co-alt-1,4-phenylene] (anionic PFP), between the aluminum (Al) cathode and emissive layer, the devices show an increased electroluminescence efficiency with a lowered turn-on voltage. We believe the mobile Na+ ions in the EIL layer directly influences the device efficiency by forming a low work function layer at the interface between the EIL and Al cathode, thereby facilitating the electron injection into the emissive layer. (C) 2008 American Institute of Physics.
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页数:3
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