Synthesis and properties of a new polymer with a cubane-containing backbone. Synthesis and metathesis polymerization and copolymerization of 1,4-bis(homoallyl)cubane

被引:18
作者
Chauvin, Y
Saussine, L
机构
[1] Inst. Francais du Petrole, 92506 Rueil-Malmaison
关键词
D O I
10.1021/ma9511715
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of an unsaturated polymer containing cubane moieties in the backbone has been achieved by acyclic diene metathesis polymerization of 1,4-bis(homoallyl)cubane. The molecular weight as determined by H-1 NMR (6-7 C14H16 repeat units) is M(n) = 1100-1300. Copolymerization of 1,4-bis(homoallyl)cubane with 1,5-hexadiene gave a polymer fraction containing an average of 9 C14H16/6 butenylene repeat units. The copolymer is soluble in THF.
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页码:1163 / 1166
页数:4
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