Imprintable, Bendable, and Shape-Conformable Polymer Electrolytes for Versatile-Shaped Lithium-Ion Batteries

被引:179
作者
Kil, Eun-Hye [1 ]
Choi, Keun-Ho [1 ]
Ha, Hyo-Jeong [1 ]
Xu, Sheng [2 ]
Rogers, John A. [2 ]
Kim, Mi Ri
Lee, Young-Gi [4 ]
Kim, Kwang Man [3 ,4 ]
Cho, Kuk Young [3 ]
Lee, Sang-Young [5 ]
机构
[1] Kangwon Natl Univ, Dept Chem Engn, Chunchon 200701, Kangwon, South Korea
[2] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61822 USA
[3] Kongju Natl Univ, Div Adv Mat Engn, Cheonan 331717, Chungnam, South Korea
[4] Elect & Telecommun Res Inst, Power Control Device Res Team, Taejon 305700, South Korea
[5] Ulsan Natl Inst Sci & Technol, Interdisciplinary Sch Green Energy, Ulsan 689798, South Korea
基金
新加坡国家研究基金会;
关键词
imprintable; bendable; shape-conformable polymer electrolytes; lithium-ion batteries; three-dimensional structured electrodes; design flexibility; UV-assisted nanoimprint lithography; STORAGE; THIN;
D O I
10.1002/adma.201204182
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A class of imprintable, bendable, and shape-conformable polymer electrolyte with excellent electrochemical performance in a lithium battery system is reported. The material consists of a UV-cured polymer matrix, high-boiling point liquid electrolyte, and Al2O3 nanoparticles, formulated for use in lithium-ion batteries with 3D-structured electrodes or flexible characteristics. The unique structural design and well-tuned rheological characteristics of the UV-curable electrolyte mixture, in combination with direct UV-assisted nanoimprint lithography, allow the successful fabrication of polymer electrolytes in geometries not accessible with conventional materials. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1395 / 1400
页数:6
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