Synthesis, crystal structure, and solution properties of a hexacopper(II) complex with bridging hydroxides, pyrazolates, and nitrates

被引：70

作者：

Sakai, K ^{[1
]}

Yamada, Y ^{[1
]}

Tsubomura, T ^{[1
]}

Yabuki, M ^{[1
]}

Yamaguchi, M ^{[1
]}

机构：

[1] TOKYO METROPOLITAN UNIV,FAC ENGN,DEPT IND CHEM,HACHIOJI,TOKYO 19203,JAPAN

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 02期

关键词：

D O I：

10.1021/ic950181j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reaction of [Cu(pzH)(4)(NO3)(2)] (pzH = pyrazole) (1) with 2 equiv of Cu(NO3)(2) . 3H(2)O at pH 6 afforded the unusual hexacopper(II) complex [Cu-3(mu(3)-OH)(mu-pz)(3)(mu(4)-NO3)(pzH)(3)](2)(mu-NO3)(2) (Pz = Pyrazolate)(2). Both 1 and 2 have been structurally characterized by X-ray diffraction. The intertrimer linkage in 2 is supported with two bridging nitrate ions. The behavior of 2 in aqueous media has been examined by means of electronic absorption spectroscopy and electric conductivity measurements.

引用

页码：542 / &

页数：4

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