Specific features of cellulose and chitin dissolution in ionic liquids of varied structure and the structural organization of regenerated polysaccharides

被引:21
作者
Bochek, A. M. [1 ]
Murav'ev, A. A. [2 ]
Novoselov, N. P. [2 ]
Zaborski, M. [3 ]
Zabivalova, N. M. [3 ]
Petrova, V. A. [1 ]
Vlasova, E. N. [1 ]
Volchek, B. Z. [1 ]
Lavrent'ev, V. K. [1 ]
机构
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[2] St Petersburg State Univ Technol & Design, St Petersburg, Russia
[3] Lodz Univ Technol, Lodz, Poland
关键词
CHITOSAN;
D O I
10.1134/S1070427212110158
中图分类号
O69 [应用化学];
学科分类号
070301 [无机化学];
摘要
Solubility of cellulose, chitin, and chitosan in seven ionic liquids of varied structure was studied. It was found that pressure, temperature, and amount of an aprotic diluent (dimethyl sulfoxide) affect the dissolution of cellulose and chitin in an ionic liquid. The variation of the degree of polymerization of cellulose and chitin in ionic liquid solutions was studied. IR Fourier spectroscopy and X-ray diffraction analysis were used to examine the structural organization of hydrated cellulose and chitin films obtained.
引用
收藏
页码:1718 / 1725
页数:8
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