Template-engaged replacement reaction: A one-step approach to the large-scale synthesis of metal nanostructures with hollow interiors

被引:850
作者
Sun, YG [1 ]
Mayers, BT [1 ]
Xia, YN [1 ]
机构
[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词
D O I
10.1021/nl025531v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper describes a general approach that generates nanoscale hollow structures of metals by reacting solutions of appropriate salt solutions with solid templates of a more reactive metal. Typical examples include Au3+, Pt2+, and Pd2+ salts and nanoparticles or nanowires of silver. The morphology, void space, and wall thickness of these hollow structures are all determined by the solid templates, which are completely converted into soluble species during the replacement reaction. Both electron microscopy and diffraction studies indicate that single crystalline hollow structures of metals can also be obtained when the templates are single crystals. These metallic hollow structures, having well-controlled sizes and shapes, are expected to find use in a number of applications that involve nanoscale encapsulation, drug delivery, plasmon photonics, and calorimetric sensing.
引用
收藏
页码:481 / 485
页数:5
相关论文
共 53 条
  • [1] Plasmon resonance shifts of Au-coated Au2S nanoshells: Insight into multicomponent nanoparticle growth
    Averitt, RD
    Sarkar, D
    Halas, NJ
    [J]. PHYSICAL REVIEW LETTERS, 1997, 78 (22) : 4217 - 4220
  • [2] Bergbreiter DE, 1999, ANGEW CHEM INT EDIT, V38, P2870, DOI 10.1002/(SICI)1521-3773(19991004)38:19<2870::AID-ANIE2870>3.0.CO
  • [3] 2-6
  • [4] Bohren C. F., 1998, ABSORPTION SCATTERIN
  • [5] Caruso F, 2001, ADV MATER, V13, P11, DOI 10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO
  • [6] 2-N
  • [7] Caruso F, 2001, ADV MATER, V13, P1090, DOI 10.1002/1521-4095(200107)13:14<1090::AID-ADMA1090>3.0.CO
  • [8] 2-H
  • [9] Electrostatic self-assembly of silica nanoparticle -: Polyelectrolyte multilayers on polystyrene latex particles
    Caruso, F
    Lichtenfeld, H
    Giersig, M
    Möhwald, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (33) : 8523 - 8524
  • [10] Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating
    Caruso, F
    Caruso, RA
    Möhwald, H
    [J]. SCIENCE, 1998, 282 (5391) : 1111 - 1114