Controlling polymer architecture through host-guest interactions

被引:57
作者
Chen, L
Zhu, XY
Yan, DY
Chen, Y
Chen, Q
Yao, YF
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
[2] E China Normal Univ, Minist Opt & Magnet Resonance Spect, Key Lab Educ, Shanghai 200062, Peoples R China
关键词
cyclodextrins; polymers; supramolecular chemistry; synthesis design;
D O I
10.1002/anie.200502306
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) A supramolecular method to control polymer architectures (see picture) is demonstrated with the synthesis of a series of poly(sulfone-amine) samples with various degrees of branching merely by changing the amount of host (β-cyclodextrin) present. Further modification of the polymer chains allows the preparation of condensation polymers with peculiar topological structures, functionalities, and properties. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:87 / 90
页数:4
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