Synthesis and structure of bishomohexaprismanedione

被引：19

作者：

Golobish, TD ^{[1
]}

Dailey, WP ^{[1
]}

机构：

[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 19期

关键词：

D O I：

10.1016/0040-4039(96)00532-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of bishomohexaprimanedione, the D-2h dimer of norbornadienone and a potential precursor to hexaprismane, is reported. The synthesis includes an unusual ring contraction of a cycloalkene using a cis-hydroxylation/periodate cleavage/aldol sequence. The structure of bishomohexaprimanedione determined from single crystal x-ray analysis is well reproduced by ab initio calculations. (C) 1996 Elsevier Science Ltd.

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页码：3239 / 3242

页数：4

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