Aqueous suspension of amphiphilic diblock copolymer nanoparticles prepared in situ from a water-soluble poly(sodium acrylate) alkoxyamine macroinitiator

被引：95

作者：

Delaittre, G ^{[1
]}

Nicolas, J ^{[1
]}

Lefay, C ^{[1
]}

Save, M ^{[1
]}

Charleux, B ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Polymeres, CNRS, UMR 7610, F-75252 Paris 05, France

来源：

SOFT MATTER | 2006年 / 2卷 / 03期

关键词：

D O I：

10.1039/b515267d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The simple, one step synthesis of aqueous suspensions of amphiphilic nanoparticles is presented. Those particles are prepared in the batch heterophase polymerization of styrene or n-butyl acrylate, using a water-soluble poly(sodium acrylate) alkoxyamine macroinitiator. The nitroxide-mediated controlled growth of the hydrophobic block leads to the formation of poly(sodium acrylate)-b-polystyrene or poly(sodium acrylate)-b-poly(n-butyl acrylate) amphiphilic diblock copolymers, able to self-assemble in water simultaneously to the growth step. When the diblock copolymers become strongly asymmetrical, with a short poly(sodium acrylate) block and a long hydrophobic one, the formed hairy nanoparticles are analogous to amphiphilic diblock copolymer crew-cut micelles.

引用

页码：223 / 231

页数：9

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