Dichloro[3-(1-naphthylmethyl)-1-(2,4,6-trimethylbenzyl)imidazolidin-2-ylidene]ruthenium

被引：9

作者：

Arslan, H ^{[1
]}

VanDerveer, D

Özdemir, I

Yasar, S

Çetinkaya, B

机构：

[1] Mersin Univ, Fac Arts & Sci, Dept Chem, TR-33343 Mersin, Turkey

[2] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

[3] Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44069 Malatya, Turkey

[4] Ege Univ, Dept Chem, TR-35100 Izmir, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2005年 / 61卷

关键词：

D O I：

10.1107/S160053680502698X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [RuCl2(C24H26N2)], the multidentate ligand functions as both an arene and a carbene, and occupies four coordination sites. The two Cl atoms complete a distorted octahedron about the Ru atom.

引用

页码：M1873 / M1875

页数：3

共 11 条

[1] Crystal structure of [RuCl2[N-(2,4,6-trimethyl-benzyl)N-(n-butyl)]-imidazolidin-2-ylidene] and [RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(2-methoxyethyl)]imidazolidin-2-ylidene] [J].

Arslan, H ;

VanDerveer, D ;

Ozdemir, I ;

Cetinkaya, B ;

Demir, S .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2005, 35 (06) :491-495

[2]

Arslan H, 2004, Z KRIST-NEW CRYST ST, V219, P377

[3]

Arslan H, 2004, Z KRIST-NEW CRYST ST, V219, P44

[4] Stable carbenes [J].

Bourissou, D ;

Guerret, O ;

Gabbaï, FP ;

Bertrand, G .

CHEMICAL REVIEWS, 2000, 100 (01) :39-91

[5] η6-mesityl,η1-imidazolinylidene-carbene-ruthenium(II) complexes:: Catalytic activity of their allenylidene derivatives in alkene metathesis and cycloisomerisation reactions [J].

Çetinkaya, B ;

Demir, S ;

Özdemir, I ;

Toupet, L ;

Sémeril, D ;

Bruneau, C ;

Dixneuf, PH .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (10) :2323-2330

[6] Synthesis and immobilization of N-heterocyclic carbene complexes of Ru(II):: catalytic activity and recyclability for the furan formation [J].

Çetinkaya, B ;

Gürbüz, N ;

Seçkin, T ;

Özdemir, I .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 184 (1-2) :31-38

[7] Synthesis and catalytic properties of N-functionalized carbene complexes of rhodium(I) and ruthenium(II) [J].

Cetinkaya, B ;

Ozdemir, I ;

Dixneuf, PH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 534 (1-2) :153-158

[8]

CETINKAYA B, 1997, J MOL CATAL, V118, P11

[9] Synthesis of a water-soluble carbene complex and its use as catalyst for the synthesis of 2,3-dimethylfuran [J].

Özdemir, I ;

Yigit, B ;

Cetinkaya, B ;

Ülkü, D ;

Tahir, MN ;

Arici, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 633 (1-2) :27-32

[10]

*RIG MSC, 1999, CRYST CLEAR REQAB

← 1 2 →