Trends in the catalytic CO oxidation activity of nanoparticles

被引：391

作者：

Falsig, Hanne ^{[2
]}

Hvolbaek, Britt ^{[1
]}

Kristensen, Iben S. ^{[1
]}

Jiang, Tao ^{[1
]}

Bligaard, Thomas ^{[1
]}

Christensen, Claus H. ^{[2
]}

Norskov, Jens K. ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Phys, Ctr Atom Scale Mat Design, DK-2800 Lyngby, Denmark

[2] Tech Univ Denmark, Dept Phys, Ctr Sustainable & Green Chem, DK-2800 Lyngby, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 26期

关键词：

carbon monoxide; density functional calculations; gold; heterogeneous catalysis; nanostructures;

D O I：

10.1002/anie.200801479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Going for gold: Density functional calculations showhowgold nanoparticles are more active catalysts for CO oxidation than other metal nanoparticles. The high catalytic activity of nanosized gold clusters at lowtemperature is found to be related to the ability of low-coordinate metal atoms to activate reactants. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4835 / 4839

页数：5

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