Unexpected synthesis of a new highly fluorocarbon soluble phosphite for biphasic catalysis

被引：21

作者：

Mathivet, T

Monflier, E

Castanet, Y

Mortreux, A

Couturier, JL

机构：

[1] Univ Artois, Lab Physicochim Interfaces & Applicat, Fac Sci J Perrin, F-62307 Lens, France

[2] Univ Sci & Tech Lille Flandres Artois, CNRS, Catalyse Heterogene & Homogene Lab, F-59652 Villeneuve Dascq, France

[3] Elf Atochem, CRRA, F-69310 Pierre Benite, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 20期

关键词：

fluorocarbons; perfluoroalkylated triarylphosphites; copper;

D O I：

10.1016/S0040-4039(99)00639-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of tris(4-(1-oxoperfluorooctyl)-2-perfluorooctylphenyl)phosphite and tris(2,4-bis(perfluorooctyl)phenyl)phosphite from commercially available 1-iodoperfluorooctane and 2,4-dibromophenol is described. The stability and the solubility of these new compounds are reported. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

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页码：3885 / 3888

页数：4

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