Synthesis of a new copper(I) complex, [Cu(tmdcbpy)2]+ (tmdcbpy=4,4′,6,6′-tetramethyl-2,2′-bipyridine-5,5′-dicarboxylic acid), and its application to solar cells

被引：99

作者：

Sakaki, S ^{[1
]}

Kuroki, T

Hamada, T

机构：

[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Hakozaki 8128581, Japan

[2] Kumamoto Univ, Fac Engn, Dept Appl Chem & Biochem, Kumamoto 8608555, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b109518h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A newly synthesized copper(I) complex, [Cu(tmdcbpy)(2)](+) (tmdcbpy = 4,4', 6,6'-tetramethyl-2,2'-bipyridine-5,5'-dicarboxylic acid), was applied to a solar cell with TiO2, which provided successful results, a photocurrent of about 4 mA cm(-2), photovoltage of 630 mV and an IPCE (incident monochromatic photon-to-current conversion efficiency) value of 30%, under visible light irradiation from a AM 1.5G sunlight simulator (100 mW cm(-2)).

引用

页码：840 / 842

页数：3

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