Different Scale Confinements of PVDF-TrFE as Functional Material of Piezoelectric Devices

被引:26
作者
Canavese, Giancarlo [1 ]
Stassi, Stefano [1 ]
Cauda, Valentina [1 ]
Verna, Alessio [1 ]
Motto, Paolo [2 ]
Chiodoni, Angelica [1 ]
Marasso, Simone Luigi [3 ]
Demarchi, Danilo [1 ]
机构
[1] Italian Inst Technol, Ctr Space Human Robot, I-10129 Turin, Italy
[2] Politecn Torino, Dept Elect & Telecommun, I-10129 Turin, Italy
[3] Politecn Torino, Dept Appl Sci & Technol, I-10129 Turin, Italy
关键词
Energy harvesting; nano-structured materials; piezoelectric effect; polymer film; tactile sensors; POLY(VINYLIDENE FLUORIDE); BETA-PHASE; CRYSTALLIZATION; FILMS;
D O I
10.1109/JSEN.2013.2248143
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this paper, we report on the effect of micro-and nano-structuration on the piezoelectric properties of polymeric samples. We prepare micro-sized pillars and nano-wires (thus 1-D structures) of a piezoelectric polymer Poly(VinyliDene Fluoride-Tri FluoroEthylene) PVDF-TrFE and we compare their structural and piezoelectrical properties with a thin film (thus 2-D) of the same material. X-ray diffraction and infrared spectroscopy measurements show that the crystallization of the polymer into the ferroelectric beta-phase is affected by the size of the confinement. The direct and converse piezoelectric characterization of the three polymeric structures shows important improvements as far as the nano-structuration is reached. As a proof of concept, we demonstrate the use of the three polymeric structures as potential flexible tactile sensors and bendable energy harvesters, showing a profound effect of the micro-and nano-structuration on the device performances.
引用
收藏
页码:2237 / 2244
页数:8
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