Nonresonant control of multimode molecular wave packets at room temperature

被引：3

作者：

Bartels, RA ^{[1
]}

Weinacht, TC

Leone, SR

Kapteyn, HC

Murnane, MM

机构：

[1] Univ Colorado, JILA, Boulder, CO 80309 USA

[2] Natl Inst Technol, Boulder, CO 80309 USA

来源：

PHYSICAL REVIEW LETTERS | 2002年 / 88卷 / 03期

关键词：

D O I：

10.1103/PhysRevB.88.033001

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We demonstrate the creation and measurement of shaped multimode vibrational wave packets with overtone and combination mode excitation in CCl4. Excitation of wave packets through nonresonant impulsive stimulated Raman scattering allows for coherent control of molecular vibrations without passing through an electronic resonance. This technique is therefore very general and can be implemented in a large class of molecular gases and liquids at STP, which were previously inaccessible because their resonances are in the VUV.

引用

收藏

页码：1 / 033001

页数：4

相关论文

共 25 条

[1] Shaped-pulse optimization of coherent emission of high-harmonic soft X-rays [J].

Bartels, R ;

Backus, S ;

Zeek, E ;

Misoguti, L ;

Vdovin, G ;

Christov, IP ;

Murnane, MM ;

Kapteyn, HC .

NATURE, 2000, 406 (6792) :164-166

[2] Vibrational state control of bimolecular reactions: Discovering and directing the chemistry [J].

Crim, FF .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (10) :877-884

[3] TIME-RESOLVED VIBRATIONAL SPECTROSCOPY IN THE IMPULSIVE LIMIT [J].

DHAR, L ;

ROGERS, JA ;

NELSON, KA .

CHEMICAL REVIEWS, 1994, 94 (01) :157-193

[4] Quantum control of ground-state rotational coherence in a linear molecule [J].

Hertz, E ;

Faucher, O ;

Lavorel, B ;

Della Via, F ;

Chaux, R .

PHYSICAL REVIEW A, 2000, 61 (03) :4-338164

[5] Optimal control of molecular states in a learning loop with a parameterization in frequency and time domain [J].

Hornung, T ;

Meier, R ;

Motzkus, M .

CHEMICAL PHYSICS LETTERS, 2000, 326 (5-6) :445-453

[6] TEACHING LASERS TO CONTROL MOLECULES [J].

JUDSON, RS ;

RABITZ, H .

PHYSICAL REVIEW LETTERS, 1992, 68 (10) :1500-1503

[7] Time resolved coherent anti-Stokes Raman scattering of I2 isolated in matrix argon:: Vibrational dynamics on the ground electronic state [J].

Karavitis, M ;

Zadoyan, R ;

Apkarian, VA .

JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (09) :4131-4140

[8]

Knopp G, 2000, J RAMAN SPECTROSC, V31, P51, DOI 10.1002/(SICI)1097-4555(200001/02)31:1/2<51::AID-JRS504>3.0.CO

[9]

2-R

[10] QUANTUM CONTROL OF WAVE-PACKET EVOLUTION WITH TAILORED FEMTOSECOND PULSES [J].

KOHLER, B ;

YAKOVLEV, VV ;

CHE, JW ;

KRAUSE, JL ;

MESSINA, M ;

WILSON, KR ;

SCHWENTNER, N ;

WHITNELL, RM ;

YAN, YJ .

PHYSICAL REVIEW LETTERS, 1995, 74 (17) :3360-3363