Triazenes as a stable diazonium source for use in functionalizing carbon nanotubes in aqueous suspensions

被引：55

作者：

Hudson, Jared L.

Jian, Huahua

Leonard, Ashley D.

Stephenson, Jason J.

Tour, James M.

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

[2] Rice Univ, Dept Mech Engn & Mat Sci, Houston, TX 77005 USA

[3] Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA

来源：

CHEMISTRY OF MATERIALS | 2006年 / 18卷 / 11期

关键词：

Molecular dynamics - Organic compounds - Reaction kinetics - Salts - Synthesis (chemical) - Vitamins;

D O I：

10.1021/cm060020l

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Organic triazene compounds are stable precursors to diazonium salts for functionalizing single-wall carbon nanotubes (SWNTs) in aqueous media. This method is particularly useful when a target molecule has functionality that will not tolerate diazotization conditions. We illustrate this by detailing the synthesis of a biotin-containing triazene followed by reaction with SWNTs.

引用

页码：2766 / 2770

页数：5

共 24 条

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