A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: Preparation of titanium and zirconium complexes and crystal structure of the titanium complex

被引：13

作者：

BarHaim, G ^{[1
]}

Shach, R ^{[1
]}

Kol, M ^{[1
]}

机构：

[1] TEL AVIV UNIV,RAYMOND & BEVERLY SACKLER FAC EXACT SCI,SCH CHEM,IL-69978 TEL AVIV,ISRAEL

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a607194e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to form a bridging amine-aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.

引用

页码：229 / 230

页数：2

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