Metal free sensitizer and catalyst for dye sensitized solar cells

被引:349
作者
Ahmad, Shahzada [1 ]
Guillen, Elena [1 ]
Kavan, Ladislav [2 ]
Graetzel, Michael [3 ]
Nazeeruddin, Mohammad K. [3 ]
机构
[1] Abengoa Res, Seville 41014, Spain
[2] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, Vvi, CZ-18223 Prague 8, Czech Republic
[3] Swiss Fed Inst Technol, Lab Photon & Interfaces, Dept Chem & Chem Engn, CH-1015 Lausanne, Switzerland
关键词
D-PI-A; NANOCRYSTALLINE TIO2 FILMS; COST COUNTER-ELECTRODE; POWER CONVERSION EFFICIENCIES; WALLED CARBON NANOTUBES; DPP-BASED SENSITIZERS; FREE ORGANIC-DYES; HIGHLY-EFFICIENT; GRAPHENE OXIDE; ELECTROPHORETIC DEPOSITION;
D O I
10.1039/c3ee41888j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The carbon neutral process for energy conversion is of utmost importance, in this context photovoltaics, especially dye sensitized solar cells (DSSCs) are a viable alternative. Few terawatts of carbon free renewable energy can be produced by DSSCs. However the judicious use of platinum group free metals may further enhance the limit of energy production by making it further cost effective. In this context a metal free sensitizer and electrocatalyst related to DSSCs are reviewed for their merits. The current state-of-the-art sensitizer as well as carbon based materials for its chemistry and photovoltaic characterization are discussed. The present article combines recent progress and its emerging behavior from our laboratories and from other groups working on this perennial topic.
引用
收藏
页码:3439 / 3466
页数:28
相关论文
共 263 条
[1]   Electrochemical synthesis and surface characterization of poly(3,4-ethylenedioxythiophene) films grown in an ionic liquid [J].
Ahmad, Shahzada ;
Deepa, M. ;
Singh, S. .
LANGMUIR, 2007, 23 (23) :11430-11433
[2]   Towards flexibility: metal free plastic cathodes for dye sensitized solar cells [J].
Ahmad, Shahzada ;
Dell'Orto, Elisa ;
Yum, Jun-Ho ;
Kessler, Florian ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
CHEMICAL COMMUNICATIONS, 2012, 48 (78) :9714-9716
[3]   A new generation of platinum and iodine free efficient dye-sensitized solar cells [J].
Ahmad, Shahzada ;
Bessho, Takeru ;
Kessler, Florian ;
Baranoff, Etienne ;
Frey, Julien ;
Yi, Chenyi ;
Graetzel, Michael ;
Nazeeruddin, Mohammad K. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (30) :10631-10639
[4]   Efficient Platinum-Free Counter Electrodes for Dye-Sensitized Solar Cell Applications [J].
Ahmad, Shahzada ;
Yum, Jun-Ho ;
Butt, Hans-Juergen ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
CHEMPHYSCHEM, 2010, 11 (13) :2814-2819
[5]   Dye-sensitized solar cells based on poly (3,4-ethylenedioxythiophene) counter electrode derived from ionic liquids [J].
Ahmad, Shahzada ;
Yum, Jun-Ho ;
Zhang Xianxi ;
Graetzel, Michael ;
Butt, Hans-Juergen ;
Nazeeruddin, Mohammad K. .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (09) :1654-1658
[6]   Donor-acceptor dyes incorporating a stable dibenzosilole π-conjugated spacer for dye-sensitized solar cells [J].
Akhtaruzzaman, Md. ;
Seya, Yohei ;
Asao, Naoki ;
Islam, Ashraful ;
Kwon, Eunsang ;
El-Shafei, Ahmed ;
Han, Liyuan ;
Yamamoto, Yoshinori .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (21) :10771-10778
[7]   Graphene-Gold Nanoparticle Composite Counter Electrode for Cobalt-electrolyte-based Dye-sensitized Solar Cells [J].
Al-Mamun, Mohammad ;
Lim, Jung-Hyurk ;
Sung, Yung-Eun ;
Kim, Sung-Ryong .
CHEMISTRY LETTERS, 2013, 42 (01) :31-33
[8]   Pt and TCO free hybrid bilayer silver nanowire-graphene counter electrode for dye-sensitized solar cells [J].
Al-Mamun, Mohammad ;
Kim, Jae-Yup ;
Sung, Yung-Eun ;
Lee, Jae-Joon ;
Kim, Sung-Ryong .
CHEMICAL PHYSICS LETTERS, 2013, 561 :115-119
[9]   Engineering Organic Sensitizers for Iodine-Free Dye-Sensitized Solar Cells: Red-Shifted Current Response Concomitant with Attenuated Charge Recombination [J].
Bai, Yu ;
Zhang, Jing ;
Zhou, Difei ;
Wang, Yinghui ;
Zhang, Min ;
Wang, Peng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (30) :11442-11445
[10]   Electrocatalysis at graphite and carbon nanotube modified electrodes: edge-plane sites and tube ends are the reactive sites [J].
Banks, CE ;
Davies, TJ ;
Wildgoose, GG ;
Compton, RG .
CHEMICAL COMMUNICATIONS, 2005, (07) :829-841