Lanthanide complexes in multifunctional asymmetric catalysis

被引:1117
作者
Shibasaki, M [1 ]
Yoshikawa, N [1 ]
机构
[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Tokyo 1130033, Japan
关键词
D O I
10.1021/cr010297z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lanthanide-based multifunctional complexes constitute a significant part of enantioselective catalysis. Thus, lanthanides are characterized by their ability to accommodate larger numbers of ligands. Accordingly, they are less prone to coordinative saturation and might allow for construction of structurally sophisticated complexes. These features make lanthanides attractive metals as a component of asymmetric catalysts.
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页码:2187 / 2209
页数:23
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