A bowl-shaped fullerene encapsulates a water into the cage

被引：149

作者：

Iwamatsu, S ^{[1
]}

Uozaki, T

Kobayashi, K

Re, SY

Nagase, S

Murata, S

机构：

[1] Nagoya Univ, Grad Sch Environm Studies, Nagoya, Aichi 4648601, Japan

[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 09期

关键词：

D O I：

10.1021/ja038537a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sequential carbon?carbon bond cleaving reactions of the diketone derivative of C 60 with o-phenylenediamine give a novel bowl-shaped fullerene bearing a 20-membered ring orifice. The product reversibly encapsulates a water molecule into the fullerene cage for the first time. Copyright © 2004 American Chemical Society.

引用

页码：2668 / 2669

页数：2

共 17 条

[1]

Frisch M.J., 1998, GAUSSIAN 98

[2] Photooxygenative partial ring cleavage of bis(fulleroid): synthesis of a novel fullerene derivative with a 12-membered ring [J].

Inoue, H ;

Yamaguchi, H ;

Iwamatsu, S ;

Uozaki, T ;

Suzuki, T ;

Akasaka, T ;

Nagase, S ;

Murata, S .

TETRAHEDRON LETTERS, 2001, 42 (05) :895-897

[3] ONIOM study of ring opening and metal insertion reactions with derivatives of C60:: Role of aromaticity in the opening process [J].

Irle, S ;

Rubin, Y ;

Morokuma, K .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (04) :680-688

[4] A novel migrative addition reaction of hydrazines to the diketone derivative of C60 [J].

Iwamatsu, S ;

Ono, F ;

Murata, S .

CHEMICAL COMMUNICATIONS, 2003, (11) :1268-1269

[5] A novel ring expansion of the holey ketolactam derivative of C60 [J].

Iwamatsu, S ;

Ono, F ;

Murata, S .

CHEMISTRY LETTERS, 2003, 32 (07) :614-615

[6]

KADISH KM, 2000, FULLERENES CHEM PHYS, pCH8

[7] 100% encapsulation of a hydrogen molecule into an open-cage fullerene derivative and gas-phase generation of H2@C60 [J].

Murata, Y ;

Murata, M ;

Komatsu, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (24) :7152-7153

[8] The reaction of fullerene C60 with 4,6-dimethyl-1,2,3-triazine:: Formation of an open-cage fullerene derivative [J].

Murata, Y ;

Murata, M ;

Komatsu, K .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (24) :8187-8191

[9] Photochemical reaction of the open-cage fullerene derivative with singlet oxygen [J].

Murata, Y ;

Komatsu, K .

CHEMISTRY LETTERS, 2001, (09) :896-897

[10] Synthesis, structure, and properties of novel open-cage fullerenes having heteroatom(s) on the rim of the orifice [J].

Murata, Y ;

Murata, M ;

Komatsu, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (07) :1600-1609

← 1 2 →