Complexes of cobalt(II), nickel(II) and copper(II) with a thia ligand;: 2,5-bis(2-pyridyl)-1,3,4-thiadiazole:: structural identification

被引:52
作者
Bentiss, F
Lagrenée, M
Wignacourt, JP
Holt, EM
机构
[1] ENSCL, Lab Cristallochim & Physicochim Solide, CNRS, UPRESA 8012, F-59652 Villeneuve Dascq, France
[2] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA
关键词
thiadiazole; M = Co; M = Ni; M = Cu; crystal structures; monomeric complexes;
D O I
10.1016/S0277-5387(01)01012-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A heterocycle, previously untested as a polydentate ligand, 2,5-bis(2-pyridyl)-1,3,4-thiadiazole, namely bptd, has been found to form the monomeric complexes, Co(bptd)(2)(H2O)(2)(NO3)(2) (I), Ni(bptd)(2)(H2O)(2)(ClO4)(2) (II), Co(bptd)(2)(H2O)(2)(ClO4)(2) (III), and Cu(bptd)(2)(NO3)(2) (IV) with Co(II), Ni(II) and Cu(II) in the presence of nitrate or perchlorate anions. Despite similar syntheses, nitrate serves as a ligand to Cu(II) in IV whereas, it is seen as a free ion in the cell of Co(bptd)(2)(H2O)(2)(NO3)(2) (I). [GRAPHICS] (I) M=Co, A=H2O, C=NO3- (II) M=Ni, A=H2O, C= ClO4 (III) M=Co, A= H2O, C= ClO4- (IV) M=Cu, A= NO3- (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:403 / 408
页数:6
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