Conductive thermoset composites: PTC effect

被引:51
作者
Boiteux, G
Fournier, J
Issotier, D
Seytre, G
Marichy, G
机构
[1] Univ Lyon 1, UMR 5627 CNRS, Etud Mat Plast & Biomat Lab, F-69622 Villeurbanne, France
[2] Soc Ferraz, F-69720 St Bonnet De Mure, France
关键词
PTC effect; conductive composites; electrical non-linearity; biphasic system; thermoset-thermoplastic matrix;
D O I
10.1016/S0379-6779(98)01432-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Positive temperature coefficient (PTC) materials art: characterised by a reversible metal to insulator transition at a defined temperature Tc. This phenomenon has been widely observed in conducting polymer composite materials such as carbon black / polyethylene compound. From a fundamental point of view, the mechanisms are still not fully understood, especially in conductive filled thermosets, which do not present a large volume expansion compared to a semicrystalline: polymer matrix. The aim of our work consists to study the properties of different conductive: epoxy composites based on mono or biphasic matrix and filled with carbon black or metallic particles. Wt: attempt to contribute to a better understanding of the: electrical non-linear phenomena in such conductive: disordered composite: materials. Analysis of the thermo-mechanical properties, percolation and conduction mechanisms are important and appear to be essential to the understanding of the PTC effect in such composites. Theoretical interpretations of the PTC anomaly will be advanced.
引用
收藏
页码:1234 / 1235
页数:2
相关论文
共 10 条
[1]   Positive temperature coefficient effect in carbon black/epoxy polymer composites [J].
Fournier, J ;
Boiteux, G ;
Seytre, G ;
Marichy, G .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (20) :1677-1679
[2]   Study of the PTC effect in conducting epoxy polymer composites [J].
Fournier, J ;
Boiteux, G ;
Seytre, G ;
Marichy, G .
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1998, 95 (06) :1510-1513
[3]  
FOURNIER J, IN PRESS J APPL PHYS
[4]  
FOURNIER J, 1997, SYNTHETIC MET, V84, P205
[5]   DESIGN OF ELECTRICAL CONDUCTIVE COMPOSITES - KEY ROLE OF THE MORPHOLOGY ON THE ELECTRICAL-PROPERTIES OF CARBON-BLACK FILLED POLYMER BLENDS [J].
GUBBELS, F ;
BLACHER, S ;
VANLATHEM, E ;
JEROME, R ;
DELTOUR, R ;
BROUERS, F ;
TEYSSIE, P .
MACROMOLECULES, 1995, 28 (05) :1559-1566
[6]   MODELS PROPOSED TO EXPLAIN THE ELECTRICAL-CONDUCTIVITY OF MIXTURES MADE OF CONDUCTIVE AND INSULATING MATERIALS [J].
LUX, F .
JOURNAL OF MATERIALS SCIENCE, 1993, 28 (02) :285-301
[7]  
Narkis M, 1997, POLYM ADVAN TECHNOL, V8, P525, DOI 10.1002/(SICI)1099-1581(199708)8:8<525::AID-PAT655>3.3.CO
[8]  
2-U
[9]  
Schueler R, 1997, J APPL POLYM SCI, V63, P1741
[10]   ELECTRON-TRANSPORT PROCESSES IN CONDUCTOR-FILLED POLYMERS [J].
SHERMAN, RD ;
MIDDLEMAN, LM ;
JACOBS, SM .
POLYMER ENGINEERING AND SCIENCE, 1983, 23 (01) :36-46