The first alkyne-dicobaltcarbonyl complex with a bidentate chiral ligand with Co-P and Co-N coordination

被引：21

作者：

Castro, J

Moyano, A

Pericàs, MA

Riera, A

Alvarez-Larena, A

Piniella, JF

机构：

[1] Univ Barcelona, Fac Quim, Dept Quim Organ, Unitat Recersa Sintesi Asimetr, E-08028 Barcelona, Spain

[2] Univ Autonoma Barcelona, Fac Ciencies, Unitat Cristallog, E-08193 Barcelona, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 585卷 / 01期

关键词：

alkyne-dicoballcarbonyl complexes; 2-(2-phosphinoaryl)dihydrooxazoles; Pauson-Khand reaction; asymmetric synthesis;

D O I：

10.1016/S0022-328X(99)00188-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the phenylacetylene dicobalthexacarbonyl complex with (R)-2-(2-diphenylphosphinophenyl)-4-phenyl-4,5-dihydrooxazole produces a 85:15 mixture of the diastereomer complexes 2 and 3 that can be separated by recrystallization; the X-ray structure of 2 shows that one cobalt atom is coordinated to both the phosphorus and nitrogen atoms of the ligand. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：53 / 58

页数：6

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