FcCH(2)P(CH2OH)(2): A new, reactive yet air-stable ferrocene-derived phosphine [Fc=(eta-C5H5)FeC5H4]

被引：20

作者：

Goodwin, NJ ^{[1
]}

Henderson, W ^{[1
]}

Sarfo, JK ^{[1
]}

机构：

[1] UNIV WAIKATO,DEPT CHEM,HAMILTON,NEW ZEALAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 13期

关键词：

D O I：

10.1039/cc9960001551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of FcCH(2)NMe(3)(+)I(-) with an excess of P(CH2OH)3 gives the air-stable ferrocenylphosphine FcCH(2)P(CH2OH)(2), characterised by an X-ray structure determination; reactivity towards reagents such as MeI, acrylonitrile and amines allows the synthesis of a range of new ferrocene-phosphine derivatives.

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页码：1551 / 1552

页数：2

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