Cubes of Zeolite A with an Amorphous Core

被引：86

作者：

Yao, Jianfeng ^{[1
]}

Li, Dan ^{[1
]}

Zhang, Xinyi ^{[1
]}

Kong, Chun-Hua ^{[3
]}

Yue, Wenbo ^{[2
]}

Zhou, Wuzong ^{[2
]}

Wang, Huanting ^{[1
]}

机构：

[1] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia

[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[3] Univ New S Wales, Electron Microscope Unit, Sydney, NSW 2052, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 44期

基金：

澳大利亚研究理事会;

关键词：

chitosan; crystal growth; hydrogels; polymers; zeolites;

D O I：

10.1002/anie.200802823

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Zeolitic jelly-donuts: Micron-sized cubes of zeolite A having a monocrystalline shell and an amorphous core were synthesized by in situ crystallization of sodium aluminosilicate gel in uncrosslinked chitosan hydrogel. Formation of cubelike core-shell structures involves particle aggregation and surface-to-core crystallization induced by the hydrogel network, and provides a new model for zeolite nucleation and growth mechanisms. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：8397 / 8399

页数：3

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