Liquid-liquid demixing from solutions of polystyrene .1. A review .2. Improved correlation with solvent properties

被引：64

作者：

Imre, A

VanHook, WA

机构：

[1] UNIV TENNESSEE, DEPT CHEM, KNOXVILLE, TN 37996 USA

[2] ATOM ENERGY RES INST, H-1525 BUDAPEST, HUNGARY

来源：

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA | 1996年 / 25卷 / 02期

关键词：

cloudpoint; consolute temperature; demixing; Hansen parameters; molecular weight dependence; phase equilibria; polymer solubility; polystyrene; scaling law; solubility parameters;

D O I：

10.1063/1.555980

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low pressure liquid-liquid demixing data for polystyrene dissolved in 76 different one-component solvent systems are reviewed and correlated. The phase diagrams are discussed, With only one exception the molecular weight of each solvent is less than that of two polystyrene monomer units. A new relation is developed which quantitatively correlates the area of solubility lying between the UCS and LCS demixing curves in the (T-c, M(w)(-1/2)) projection with solvent solubility parameters. (C) 1996 American Institute of Physics and American Chemical Society.

引用

页码：637 / 661

页数：25

共 131 条

[1]

Allen G., 1965, POLYMER, V6, P181

[2]

ARNAUTS J, 1993, MAKROMOL CHEM, V194, P77

[3]

ARNAUTS J, 1987, POLYM COMMUN, V28, P66

[4]

BABA Y, 1973, MAKROMOL CHEM, V164, P349