Comparison of microbiologically and enzymatically mediated Baeyer-Villiger oxidations: Synthesis of optically active caprolactones

被引：37

作者：

Alphand, V

Furstoss, R

PedragosaMoreau, S

Roberts, SM

Willetts, AJ

机构：

[1] FAC SCI LUMINY,GRP CHIM ORGAN & BIOORGAN,URA CNRS 1320,F-13288 MARSEILLE 9,FRANCE

[2] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

[3] UNIV EXETER,DEPT BIOL SCI,EXETER EX4 4QD,DEVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 15期

关键词：

D O I：

10.1039/p19960001867

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active a-substituted caprolactones (7-substituted oxepan-2-ones) were obtained by biocatalysed Baeyer-Villiger oxidations of various a-substituted cyclohexanones using either whole-cells of Acinetobacter TD63 or a purified cyclohexanone monooxygenase from Ps. putida NCIMB 10007(MO2). A refinement of the previously established active site model is proposed.

引用

页码：1867 / 1872

页数：6

共 36 条

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