The structural characterisation and elucidation of the electronic structure of the mononuclear Pt(III) complex [Pt([9]aneS3)2]3+ ([9] aneS3=1,4,7-trithiacyclononane)

被引：21

作者：

Stephen, Emma ^{[1
]}

Blake, Alexander J. ^{[1
]}

Davies, E. Stephen ^{[1
]}

McMaster, Jonathan ^{[1
]}

Schroder, Martin ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 44期

关键词：

D O I：

10.1039/b811645h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mononuclear Pt(III) complex, [Pt([9]aneS(3))(2)](3+), has been isolated and characterised by X-ray crystallography; its electronic structure determined by EPR spectroscopy and DFT calculations.

引用

页码：5707 / 5709

页数：3

共 22 条

[1] Synthesis and crystal and electronic structures of the dinuclear platinum compounds [PEtPh3]2[Pt2(μ-PPh2)2(C6F5)4] and [Pt2(μ-PPh2)2(C6F5)4]:: A computational study by density functional theory [J].

Alonso, E ;

Casas, JM ;

Cotton, FA ;

Feng, XJ ;

Forniés, J ;

Fortuño, C ;

Tomas, M .

INORGANIC CHEMISTRY, 1999, 38 (22) :5034-5040

[2] A series of transition metal bis(dicyanobenzenedithiolate) complexes [M(dcbdt)2] (M= Fe, Co, Ni, Pd, Pt, Cu, Au and Zn) [J].

Alves, H ;

Simao, D ;

Santos, IC ;

Gama, V ;

Henriques, RT ;

Novais, H ;

Almeida, M .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (06) :1318-1329

[3] X-RAY CRYSTAL-STRUCTURE OF THE PENTAGONAL BIPYRAMIDAL NICKEL(II) COMPLEX [NIII(L)(H2O)2](BF4)2 AND THE SELECTIVE STABILIZATION OF THE NICKEL(I) OXIDATION-STATE BY A QUINQUEDENTATE MACROCYCLIC LIGAND [J].

ANSELL, CWG ;

LEWIS, J ;

RAITHBY, PR ;

RAMSDEN, JN ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (10) :546-547

[4] TETRAMETHYLDIPLATINUM(III) (PT-PT) COMPLEXES WITH 2-HYDROXYPYRIDINATO BRIDGING LIGANDS [J].

BANCROFT, DP ;

COTTON, FA ;

FALVELLO, LR ;

SCHWOTZER, W .

INORGANIC CHEMISTRY, 1986, 25 (06) :763-770

[5] TETRAMETHYLDIPLATINUM(III) (PT-PT) COMPLEXES WITH 2-HYDROXYPYRIDINATO BRIDGING LIGANDS .3. COMPOUNDS WITH DIETHYL SULFIDE AS THE AXIAL LIGAND [J].

BANCROFT, DP ;

COTTON, FA .

INORGANIC CHEMISTRY, 1988, 27 (22) :4022-4025

[6] PI-EFFECTS IN THIOETHER MACROCYCLIC COMPLEXES - THE STABILIZATION AND STRUCTURE OF THE LOW-SPIN FE-3 THIOETHER COMPLEX [FE([9]ANES3)2]3+ [J].

BLAKE, AJ ;

HOLDER, AJ ;

HYDE, TI ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) :1433-1434

[7] SYNTHESIS, STRUCTURES, AND ELECTROCHEMISTRY OF PALLADIUM AND PLATINUM MACROCYCLIC COMPLEXES OF [18]ANEN2S4 (1,4,10,13-TETRATHIA-7,16-DIAZACYCLO-OCTADECANE) AND ME2[18]ANEN2S4 (7,16-DIMETHYL-1,4,10,13-TETRATHIA-7,16-DIAZACYCLO-OCTADECANE) - SINGLE-CRYSTAL X-RAY STRUCTURES OF [PD(ME2[18]ANEN2S4)][PF6]2.ME2CO, [PD([18]ANEN2S4)][BPH4]2, AND [PD2CL2([18]ANEN2S4)][PF6]2.2MECN [J].

BLAKE, AJ ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (11) :3363-3373

[8] STABILIZATION OF TRIVALENT PLATINUM BY STRUCTURALLY ACCOMMODATING THIAMACROCYCLES [J].

BLAKE, AJ ;

GOULD, RO ;

HOLDER, AJ ;

HYDE, TI ;

LAVERY, AJ ;

ODULATE, MO ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (02) :118-120

[9] STABILIZATION OF MONO-VALENT PALLADIUM BY TETRA-AZA MACROCYCLES [J].

BLAKE, AJ ;

GOULD, RO ;

HYDE, TI ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (06) :431-433

[10] Structural studies of [Pt(CNMe)4][M(mnt)2]n {M = Pd or Pt, mnt = [S2C2(CN)2]2-, n = 1 or 2}:: structure-dependent paramagnetism of three crystal forms of [Pt(CNMe)4][Pt(mnt)2]2 [J].

Bois, H ;

Connelly, NG ;

Crossley, JG ;

Guillorit, JC ;

Lewis, GR ;

Orpen, AG ;

Thornton, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (17) :2833-2838

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