Elongated dihydrogen complexes:: what remains of the H-H Bond?

被引：166

作者：

Heinekey, DM ^{[1
]}

Lledós, A

Lluch, JM

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

[2] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2004年 / 33卷 / 03期

关键词：

D O I：

10.1039/b304879a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Of the several hundred examples of transition metal dihydrogen complexes that have been reported to date, the vast majority have H-H distances of less than 1.0 Angstrom. A small number of complexes have been reported with distances in the range of 1.1 to 1.5 Angstrom. These complexes have been termed elongated dihydrogen complexes. In this review, experimental methods for structure determination of such complexes are summarized, along with computational approaches which have proven useful in understanding the structures of these molecules.

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页码：175 / 182

页数：8

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