Association of two incomplete cubane WS3Cu3 clusters in the crystal structures of [PPh(4)](2)[{(C(5)Me(5))WS3}(2) Cu-6(NCS)(6)] and [PPh(4)](2)[{(C(5)Me(5))WS3}2Cu6Br6]

被引：52

作者：

Lang, JP ^{[1
]}

Kawaguchi, H ^{[1
]}

Ohnishi, S ^{[1
]}

Tatsumi, K ^{[1
]}

机构：

[1] NAGOYA UNIV,FAC SCI,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 46401,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 04期

关键词：

D O I：

10.1039/a608131b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-double cubane-like clusters, [PPh(4)](2)[{(C(5)Me(5))-WS3}2CU6(NCS)(6)] 1 and [PPh(4)](2)[{(C(5)Me(5))WS3}2Cu6Br6] 2, are self-assembled by the reactions of [PPh(4)][(C(5)Me(5))WS3] with CuNCS and CuBr in acetonitrile, respectively, the crystal structures of which consist of two WS3Cu3 incomplete cubes linked by NCS and Br bridges.

引用

页码：405 / 406

页数：2

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